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Vol. 1 No. 1 (2026): Chimica nella Scuola n. 1 2026

I cent’anni della Meccanica Quantistica

  • Giovanni Villani
DOI:
https://doi.org/10.1473/3gxhb882
Submitted
7 April 2026
Published
7 April 2026

Abstract

The United Nations General Assembly has designated 2025 as the “International Year of Quantum Science and Technology”. Quantum science, in fact, provides the foundation for basic research and the interpretation of the atomic/molecular world, and its beginning can be dated back to the works of Heisenberg and Pauli in 1925. The study of the molecular world, however, did not begin that year. Nineteenth-century chemists, in fact, developed useful concepts in this world and connected them to the macroscopic properties of chemical substances. In this educational paper, we intend to discuss the conceptual aspects and “open issues” of the relationship between quantum mechanics and the historical concepts of chemistry. Although this physical theory represented a revolutionary change in the study of the atomic/molecular world, it still struggles to gain traction in the educational and general/cultural contexts, both for “objective” reasons and due to the current lack of attention to the analysis of the conceptual/philosophical problems of this theory and their educational treatment.

References

  1. [1] M. P. Banchetti-Robino, G. Villani, From the Atom to Living Systems. A Chemical and Philosophical Journey into Modern and Contemporary Science, Oxford University Press, New York, 2023, pp. 55-59.
  2. [2] E. Ghibaudi, L. Cerruti, G. Villani, Structure, shape, topology: entangled concepts in molecular chemistry, Foundations of Chemistry, 2020, 22, 279-307.
  3. [3] G. Villani, M. V. Cubellis, Overview of the complex but fruitful relationship between molecular chemistry and quantum mechanics, in celebration of the Year of Quantum Sciences and Technologies, Top Italian Scientists Journal, 2025, 2(4) (https://www.doi.org/10.62684/JDPO8893).
  4. [4] O. Lombardi, G. Villani, About the concept of molecular structure, Foundations of Science, 2024 (https://doi.org/10.1007/s10699-024-09963-y).
  5. [5] G. Villani, La chiave del mondo. Dalla filosofia alla scienza: l’onnipotenza delle molecole, CUEN, Napoli, 2001, pp. 129-144.
  6. [6] G. Villani, Complesso e organizzato. Sistemi strutturati in fisica, chimica, biologia ed oltre, FrancoAngeli, Milano, 2008, pp. 58-62.
  7. [7] P. Machamer, L. Darden, C. Craver, Thinking about mechanisms, Philosophy of Science, 2000, 67, 1-25.
  8. [8] W. Bechtel, Mechanism and Biological Explanation, Philosophy of Science, 2011, 78, 533-557.
  9. [9] R. F. Hendry, Mechanisms in Chemistry, in New Mechanism. Explanation, Emergence and Reduction, J. L. Cordovil, G. Santos, D. Vecchi, D. (Eds.), Cham:Springer, 2023, 35, 139-160.
  10. [10] R. Marcelin, Contribution a l’étude de la cinétique physico-chimique. Annales de Physique, 1915, 9(3), 120-231.
  11. [11] H. Eyring, The activated complex in chemical reactions, Journal of Chemical Physics, 1935, 3, 107-115.
  12. [12] M. G. Evans, M. Polanyi, Further considerations on the thermodynamics of chemical equilibria and reaction rates, Trans. Faraday Soc., 1936, 32, 1333-1360.
  13. [13] M. G. Evans, M. Polanyi, Inertia and driving force of chemical reactions, Trans. Faraday Soc., 1938, 34, 11-24.
  14. [14] H. Eyring, Men, mines, and molecules, Annual Review of Physical Chemistry, 1977, 28, 1-15.
  15. [15] M. C. Gupta, Statistical thermodynamics, New Age International Publishers, New Delhi, 2007.
  16. [16] S. G. Christov, Historical Introduction, in Collision Theory and Statistical Theory of Chemical Reactions, Lecture Notes in Chemistry, Springer, Berlin, Vol. 18, 1980.
  17. [17] J. O. Hirshfelder, E. Wigner, Some quantum‐mechanical considerations in the theory of reactions involving an activation energy, J. Chem. Phys., 1939, 7, 616-628.
  18. [18] G. Villani, A time-dependent quantum approach to allostery and a comparison with light-harvesting in photosynthetic phenomenon, Frontiers in Molecular Biosciences, 2020, 7 (https://doi.org/10.3389/FMOLB.2020.00156).
  19. [19] R. Blonder, et al., Teaching quantum mechanics concepts through problem solving, Physics Education, 2014, 49(2), 208-213.
  20. [20] P. R. L. Heron, et al., Quantum mechanics and the role of interpretation in high school education, Physics Education, 2017, 52(6), 065004.
  21. [21] H. Friedrich, G. Holton, Teaching quantum mechanics at the high school level, Journal of Physics Education, 2003, 42(2), 81-84.
  22. [22] A. Lurio, Teaching quantum mechanics: challenges and innovations, Physics Education, 2001, 36(1), 9-12.
  23. [23] R. Chabay, B. Sherwood, Quantum mechanics: A new approach for teaching and learning, Physics Education, 2010, 45(5), 474-481.
  24. [24] G. Villani, Studiare gli atomi e le molecole nei licei. Alcune considerazioni generali, Nuova Secondaria, 2020, XXXVIII(2), 42-45.
  25. [25] U. Cosentino, M. Venanzi, Percorsi didattici di introduzione alla Meccanica Quantistica, in I tanti volti della chimica. Percorsi innovativi per insegnarla e comprenderla (a cura di E. Aquilini, E. Ghibaudi, M. Venturi, G. Villani), CLUEB, Bologna, 2024, pp. 323-351.
  26. [26] D. Wick, D. Finkelstein, Using interactive simulations to teach quantum mechanics, International Journal of Quantum Chemistry, 2015, 115(6), 369-377.
  27. [27] D. Smith, R. Hemmings, Exploring quantum mechanics through virtual labs and simulations, Journal of Educational Technology Systems, 2020, 49(4), 483-501.
  28. [28] C. A. L. Mahunyag, et al., ELQUAN: A game-based learning tool to master electron configuration and quantum numbers, Journal of Chemical Education, 2025, 102(1), 444-451.
  29. [29] E. Ghibaudi, G. Villani, L’approccio scientifico alla realtà: una riflessione epistemologica, in I tanti volti della chimica. Percorsi innovativi per insegnarla e comprenderla (a cura di E. Aquilini, E. Ghibaudi, M. Venturi, G. Villani), Bologna, 2024, CLUEB, Bologna, 2024, pp. 23-36.
  30. [30] T. Traube, R. Blonder, A computational chemistry course for teachers: From research laboratories to high-school chemistry teaching, Journal of Chemical Education, 2023, 100(11), 4360-4368.

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